【正文】 斷地探索，新奇的配合物不斷涌現(xiàn)。當(dāng)然，這類配合物精心設(shè)計(jì)和調(diào)控已成為這一領(lǐng)域中的挑戰(zhàn)性課題。因此對(duì)此類配合物進(jìn)行半定向的合成，進(jìn)而為探索物質(zhì)結(jié)構(gòu)和功能間的關(guān)系，為此類配合物在化學(xué)研究、光電材料、磁性材料等方面的應(yīng)用提供理論與實(shí)驗(yàn)基礎(chǔ)。江蘇大學(xué)本科畢業(yè)論文—16—致謝本論文是在______老師精心指導(dǎo)下完成的。在課題完成的過程中，______老師給與我諸多的幫助，特別是在實(shí)驗(yàn)過程中，遇到很多問題，自己無(wú)法解決時(shí)，總會(huì)和我一起思考，探討實(shí)驗(yàn)配方等。在______老師的悉心指導(dǎo)下，我的實(shí)踐能力得到很大的提高。_______老師嚴(yán)謹(jǐn)?shù)闹螌W(xué)態(tài)度、淵博的專業(yè)知識(shí)、豐富的實(shí)踐經(jīng)驗(yàn)、開闊的視野、敏銳的觀察力給我留下了深刻的印象，使我終生受益。在此對(duì)老師表示由衷的感謝。(本部分內(nèi)容同學(xué)可以自己進(jìn)行發(fā)揮)江蘇大學(xué)本科畢業(yè)論文—17—參考文獻(xiàn)[1] Lo S. M. F., Chui S. S. Y., Shek L. Y.，Lin Z. Y.，Zhang X. X. , Wen G. H.. Solvothermal Synthesis of a Stable Coordination Polymer with CopperII DimerUnits:[Cu4{1，4C6H4(COO)2(4, 4′bipy)2n.[J]. Am. Chem. Soc., 2022, 122(26): 293294.[2] Lu J .Y.，Babb A. M.. A Simultaneous Reduetion, Substitution,and SelfAssembly Reaction under Hyd rothermal Conditions Aflbrdedthe First Diiodopyridine Copper(I) Coordination polymer.[J]. In. Chem.，2022 ，41(6): 13391341.[3] HirsehK. A.,Wilson S. R.,Moore J. S.. Coordination Networks of 3,3′Dicyanodiphenylacetylene and Silver(I) Salts: Structural Diversity through Changes in Ligand Conformationand Counterion. [J].Inors. Chem.,1997,36(14: 2960 2968.[4] [M].科學(xué)技術(shù)文獻(xiàn)出版社， 2022: 1300.[5] 沈昊宇，[J].化學(xué)通報(bào)，1998，10:1416.[6] Lin W. ,Evans O. R., Xiong R. G.,Wang Z.. Supramolecular Engineering of Chiral and Acentric 2D Networks, Synthesis，Struetures， and Second Order Nonlinear Optical Properiies of Bis(nieotinato) zinc and Bis{3[2(4Pyridyl)ethenyl]benzoato}cadmium.[J]. . Chem. Soc.，1998，120(50):1327213281.[7] VSlone R., Hupp J. T. , Stern . and . SelfAssembly of Luminescent Molecular Squares Featuring Oetahedral Rhemium Comers.[J]. .，1996，35(l4):40964099.[8] Gerhard F. S., Tshepo J. M.. New SelfAssembled Structural Motifs in Coordination Chemistry.[J].Chem. Rev.,2022,100(9): 34833537.[9] Bradley J. H., Chad A. M.. Strategies for the Construction of Supramolecular Compounds through Coordination Chemistry.[J]. .,2022,40(11): 20222043.[10] Yu K. B.. structure of catenaPoly{bis(1,1,1trifluoro2，4pentanedionatok 2o,o’) copper u[(4,4 bipydine)kN:kN’]}.[J]. ,1991,47(12): 26532661.[11] Yahghi O. M.,Li H., Groy T. L.. A Molecular Railroad with large Pores:Synthesis and Structure of Ni(4, 4’bPy)2(H2O)2(ClO4)2(4,4’bPy)2H2O.[J]. In. Chem., 1997, 36(20): 42924305.[12] Tong M. L.,Ye B. H.,Cai J. W., Chen X. M., Ng S. W.. Clathration of TwoDimensional Coordination polymers: Synthesi and Struetures of [M(4,4’bpy)2(H2O)2](ClO4)2(2,2’bpy)2H2O and[Cu(4,4’bpy)2(H2O)2(ClO4)2(4,4’H2bPy)2(M=CdII,ZnII,andbpy=Bipyridine).[J]..,1998,37(11): 26452648.江蘇大學(xué)本科畢業(yè)論文—18—[13] Fujita M.,Kwon Y. J.,Sasaki O.,Yamaguchi K.,Ogura K.. Interperating Molecular Ldders and Bricks.[J]. ., 1995, 117(27): 72877301.[14] Yaghi O. M., Li H.. Hydrothermal Synthesis of a MetalOrganic Frame Work Containing Large Rectangular Channels.[J]. .,1995, 117(41): 1040110416.[15] Soma T., Yuge H., Iwamoto T..ThreeDimensional Interperating Double and Triple Framework Structures in [Cd(bpy)2{Ag(CN)2}2 and [Cd(pyrz){Ag2(CN)3}{Ag(CN)2}].[J]. Angrew. . EngL., 1994,33(16): 16651677.江蘇大學(xué)本科畢業(yè)論文—19—Hydrothermal Synthesis and Crystal Structure of a Copper Complex with Terephthalic acid and Medpq LigandsAbstract: A metalanic coordination pound formulated as [Cu(MOPIP)(BDC)]n(H2O)1(MOPIP = 2(4methoxyphenyl)1Himidazo[4,5f][1,10] phenanthroline, BDC = 1,4benze Nedicar boxylate) has been hydrothermally synthesized and structurally characterized by elemental analysis, thermogravimetric analysis, IR spectrum, and singlecrystal Xray diffraction. The title pound crystallizes in the triclinic system, space group P1, with a = (5) 197。, b = (6) 197。, c = (6) 197。, α = (7) 176。, β = (6) 176。, γ = (7)176。, V = (12) 197。3, , Mr = , Dc = g/cm3, μ(MoKα) = mm, F(000) = 576, Z = 2, the final R = and wR = for 3419 observed reflections (I 2σ(I)). Keywords: Copper Complex； Crystal Structure； Hydrothermal Synthesi