化學(xué)高中有機(jī)化學(xué)物理性質(zhì)-資料下載頁
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【正文】 。29. [C6H7O2(OH)3]n + 3nCH3COOH 濃H2SO4→ [C6H7O2(OOCCH3)3]n + 3nH2O30. 葡萄糖 + 乙酸 乙酸酐五. 水解(鹵代烴、酯、油脂的水解見上,亦是取代反應(yīng))31. CH3COONa + H2O→CH3COOH + NaOH32. CH3CH2ONa + H2O →CH3CH2OH + NaOH33. C6H5ONa + H2O→ C6H5OH + NaOH34. C17H35COONa + H2O→ C17H35COOH + NaOH35. (C6H10O5)n + nH2O淀粉酶→ nC12H22O11淀粉 麥芽糖36. 2(C6H10O5)n + nH2O H2SO4,加熱→ nC6H12O6淀粉 葡萄糖37. (C6H10O5)n + nH2O H2SO4,常時(shí)間加熱→ nC6H12O6纖維素 葡萄糖38. C12H22O11 + H2O H2SO4 →C6H12O6 + C6H12O6 蔗糖 葡萄糖 果糖39. C12H22O11 + H2O H2SO4 →2C6H12O6麥芽糖 葡萄糖40. 蛋白質(zhì)胃蛋白酶或胰蛋白酶→ 各種a氨基酸六. 氧化反應(yīng)(一)被強(qiáng)氧化劑氧化41. 2C2H5OH + O2 Cu或Ag →2CH3CHO + 2H2O42. C6H12O6+ 6O2 → 6CO2 + 6H2O + 熱43. 2CH3CHO + O2 →2CH3COOH★44. 5CH2=CH2 + 6KMnO4 + 18H2SO4 → 6K2SO4 + 10CO2 + 12MnSO4 +28H2O★45. 5C6H5CH3 + 6KMnO4 + 9H2SO4 →5C6H5COOH + 3K2SO4 + 6MnSO4 + 14H2O★46. 5C6H5CH2CH3 + 12KMnO4 + 18H2SO4→ 5C6H5COOH + 5CO2 + 6K2SO4 + 12MnSO4 + 28H2O(二)被弱氧化劑氧化48. CH3CHO + 2Cu(OH)2 加熱 →CH3COOH + Cu2O↓ + 2H2O(CHOH)4CHO+2[Ag(NH3)2]OH→CH2OH(CHOH)4COONH4+2Ag↓+3NH3+ H2O(CHOH)4CHO+2Cu(OH)2加熱 →CH2OH(CHOH)4COOH + Cu2O↓ + 2H2O51. HCOOH + 2[Ag(NH3)2]OH→ NH4HCO3 + 2Ag↓ + 3NH3 + H2O52. HCOOH + 2Cu(OH)2 加熱 →CO2 + Cu2O↓ + 3H2O53. HCOONa + 2[Ag(NH3)2]OH→ NaHCO3 + 4NH3 + 2Ag↓ + H2O54. HCOONH4 + 2[Ag(NH3)2]OH→ NH4HCO3 + 2Ag↓ + 4NH3 + H2O55. HCOOR + 2[Ag(NH3)2]OH →NH4OCOOR + 2Ag↓+ 3NH3 + H2O56. HCHO + 2[Ag(NH3)2]OH → HCOONH4 + 2Ag↓ + 3NH3 + H2O57. HCHO + 4[Ag(NH3)2]OH → NH4HCO3 + 4Ag↓+ 7NH3 + 2H2O58. HCHO + 4Cu(OH)2 加熱 →CO2 + 2Cu2O↓ + 5H2O七. 還原反應(yīng)59. CH3COCH3 + H2 Ni →CH3CHOHCH3 60. HCHO + H2 Ni →CH3OH61. C6H5CH=CH2 + 4H2 Ni →C6H11CH2CH3八. 加聚反應(yīng)62. nCH2=CH2 → [ CH2CH2 ]n 63. nCH3CH=CH2 → [ CHCH2 ]n64. nCH2=CHX →[ CH2CH ]n 65. nCF2=CF2→ [ CF2CF2 ]n66. nCH2=CHCN → [ CH2CH ]n 67. nCH2=CCOOCH3→ [ CH2C ]n68. nCH2=CCH=CH2 → [ CH2C=CHCH2 ]n69. nCH2=CHCH=CH2 → [ CH2CH=CHCH2 ]n70. nCH2=CHCH=CH2 + nC6H5CH=CH2 →[ CH2CH=CHCH2CH2CH ]n或[ CH2CH=CHCH2CHCH2 ]n71. 3CH CH→ C6H6 (苯) 72. nCH2=CH2 + nCH3CH=CH2 →[ CH2CHCH2CH2 ]n 或 [ CHCH2CH2CH2 ]n九. 縮聚反應(yīng)72. HNCH2COH + HNCH2COH + ... → HNCH2CNCH2C ... + nH2O73. nC6H5OH + nHCHO濃HCl,加熱→ [ C6H3OHCH2 ]n + nH2O74. HOOC COOH + nHOCH2CH2OH → [ CO COOCH2CH2O ]n + 2nH2O十. 其他(一)有機(jī)物跟鈉的反應(yīng)75. 2CH3CH2OH + 2Na → 2CH3CH2ONa + H276. 2C6H5OH + 2Na → 2C6H5ONa + H2↑77. 2CH3COOH + 2Na→ 2CH3COONa + H2 ↑(二)炭化78. C12H22O11 濃H2SO4 →12C + 11H2O(三)分子間脫水79. 2C2H5OH 濃H2SO4,140℃ →C2H5OC2H5 + H2O(四)氨基酸的兩性80. CH2COOH + HCl → [ CH2COOH ]Cl81. CH2COOH + NaOH → CH2COONa + H2O
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