【文章內(nèi)容簡(jiǎn)介】 ......... 61 大分子引發(fā)劑的制備 ............................................................................................................ 61 測(cè)試與表征 ............................................................................................................................ 61 結(jié)果和討論 ............................................................................................................................... 62 大 分子引發(fā)劑的制備以及表征 ............................................................................................ 62 大分子引發(fā)劑的擴(kuò)鏈反應(yīng) .................................................................................................... 63 小結(jié) ........................................................................................................................................... 65 第五章 結(jié)論 ................................................................................................... 67 VI 目 錄 參考文獻(xiàn) ..........................................................................................................................69 致 謝 ...............................................................................................................................75 研究成果及發(fā)表的學(xué)術(shù)論文 .....................................................................................77 作者及導(dǎo)師簡(jiǎn)介 ............................................................................................................79 VII 北京化工大學(xué)碩士學(xué)位論文 Contents Chapter 1 Introduction ............................................................................................... 1 Preface ..............................................................................................................................1 Principle of Living radical polymerization............................................................................2 Several successful LRP systems ..........................................................................................3 Iniferter ...........................................................................................................................3 Stable free radical control polymerization ..........................................................................7 Atom transfer radical polymerization ..............................................................................10 Reversible addition fragmentation chain transfer polymerization ....................................12 Other LRP systems ...........................................................................................................15 OrganotelluriumMediated Living Radical Polymerization ...............................................15 SingleElectron Transfer Living Radical Polymerization ..................................................15 Reversible chain transfer catalyzed polymerization， RTCP..............................................16 ThioketoneMediated Polymerization ..............................................................................17 Applications of LRP .........................................................................................................18 Preparation of block polymer copolymer .........................................................................18 Modification of surface ..................................................................................................20 Purpose and significance of the thesis ................................................................................22 Chapter 2 Synthesis and Characterization of the initiator ..........................25 Preface ............................................................................................................................25 Experimental section ........................................................................................................25 Experimental materials ...................................................................................................25 Synthesis of Bixan .........................................................................................................26 Synthesis of XNMPN ....................................................................................................26 Characterization ............................................................................................................26 Results and discussion ......................................................................................................27 The influence of different conditions on the synthesis of XNMPN ....................................27 Characterization of Bixan ...............................................................................................29 Characterization of XNMPN ..........................................................................................30 VIII 目 錄 Summary .........................................................................................................................31 Chapter 3 Study of polymerization initiated by XNMPN ............................33 Perface ............................................................................................................................33 Experimental section ........................................................................................................34 Experimental materials ...................................................................................................34 Bulk polymerzation .......................................................................................................34 Solution polymerization .....................................