【正文】 the synthesis of waterborne polyurethane and modification research is also like a raging fire. This paper mainly studied the structure and the properties of the waterborne polyurethane, preparation, in flame retardant agent to discuss the analysis of the flame retardant classification, inanic flame retardant agent。 In the electronic label application of waterborne polyurethane in the analysis, this paper discusses the crosslinking type PUA posite emulsion, selfcrosslinking PUA posite emulsion, interperating work PUA posite emulsion, epoxy resin modified waterborne polyurethane emulsion, finally the electronic tag antenna base material application research. Research shows that the FRC 6 to substitute other small molecule glycol chain extension agent, can synthesize more stable anophosphorous flame retardant modification of waterborne polyurethane。 Will DMAc as solvent, can improve the efficiency of prepolymerization body reaction. If you need to get appearance translucence emulsion, pre polymers in DMBA dosage must be controlled in 5%. Key words: waterbased polyurethane。 Inanic flame retardant agent。 RFIF base material 目錄 IV 目 錄 摘 要 ......................................................... I Abstract....................................................... II 第一章 緒論 ..................................................... 1 課題來(lái)源 ................................................................................................. 1 國(guó)內(nèi)外研究現(xiàn)狀 ..................................................................................... 1 當(dāng)前存在的問(wèn)題 ..................................................................................... 2 本文研究?jī)?nèi)容 ......................................................................................... 3 第二章 水性聚氨酯分析 ........................................... 4 水性聚氨酯制備概述 .............................................................................. 4 水性聚氨酯的合成 ....................................................................... 4 水性聚氨酯的改性 ...................................................................... 5 水性聚氨酯的結(jié)構(gòu)與性能 ..................................................................... 8 水性聚氨酯的制備 ............................................................................... 11 阻燃劑 .................................................................................................... 12 阻燃劑的分類(lèi) ............................................................................. 13 無(wú)機(jī)阻燃劑 ................................................................................. 13 阻燃劑阻燃的基本原理 ....................................................................... 15 凝聚相阻燃 機(jī)理 ........................................................................ 15 自由基捕獲機(jī)理 ......................................................................... 16 冷卻機(jī)理 ..................................................................................... 16 協(xié)同阻燃機(jī)理 ............................................................................. 16 水性聚氨酯的阻燃的應(yīng)用研究現(xiàn)狀 ................................................... 17 第三章 有機(jī)磷阻燃改性水性聚氨酯 ................................ 19 簡(jiǎn)介 ....................................................................................................... 19 實(shí)驗(yàn)過(guò)程 ............................................................................................... 20 實(shí)驗(yàn)基本材料 ............................................................................ 20 有機(jī)磷阻燃改性水性聚氨酯的合成 ......................................... 20 目錄 V 3. 3 性能測(cè)試 .............................................................................................. 21 膠膜的處理和制造 ..................................................................... 21 紅外光譜的檢測(cè) ......................................................................... 22 膠膜耐水性的檢測(cè) ..................................................................... 22 乳液穩(wěn)定性測(cè)試 ......................................................................... 22 乳液粒徑測(cè)試 ............................................................................. 22 熱重 測(cè)試 ..................................................................................... 22 極限氧指數(shù)測(cè)試 ......................................................................... 22 結(jié)果分析 ............................................................................................... 22 紅外光譜分析 ............................................................................. 23 . 2 預(yù)聚體中 P 的含量影響 WPU 乳液外觀、穩(wěn)定性及膠膜性能...................................................................................................................... 24 . 3 預(yù)聚體中 P 含量影響 WPU 乳液粒徑 .................................... 25 不同 P 含量的 PU 膠膜的 熱重研究 ........................................ 26 . 5 微型燃燒量熱研究 .................................................................... 27 極限氧指數(shù)及垂直燃燒研究 ..................................................... 28 本章小結(jié) ................................................................................................ 29 第四章 電子標(biāo)簽應(yīng)用中水性聚氨酯的分析 .......................... 30 簡(jiǎn)介 ....................................................................................................... 30 電子標(biāo)簽 水性聚氨酯的研究背景 ..................................................... 30 交聯(lián)型 PUA 復(fù)合乳液 ............................................................... 30 自交聯(lián)型 PUA 復(fù)合乳液 .......................................................... 31 互穿網(wǎng)絡(luò)型 PUA 復(fù)合乳液 ...................................................... 31 環(huán)氧樹(shù)脂改性水性聚氨酯乳液 ................................................ 31 聚硅氧烷改性 ............................................................................ 32 納米材料復(fù)合改性 ..................................................................... 32 水性聚氨酯膠粘劑的交聯(lián)方式 ................................................. 32 電子標(biāo)簽天線基材中應(yīng)用研究 ........................................................... 33 RFID 天線 ................