【正文】 J I A N G S U U N I V E R S I T Y本 科 畢 業(yè) 論 文由對苯二甲酸構(gòu)筑的銅的配位聚合物的水熱合成及晶體結(jié)構(gòu)Hydrothermal Synthesis and Crystal Structure of a Copper Complex with Terephthalic acid and Medpq Ligands學(xué)院名稱： 化學(xué)化工學(xué)院專業(yè)班級： 化學(xué)工程與工藝 12 級學(xué)生姓名：學(xué) 號：指導(dǎo)教師姓名：指導(dǎo)教師職稱：2022 年 3 月江蘇大學(xué)本科畢業(yè)論文—I—目錄第一章 文獻綜述 .................................................................................................................................1 配位聚合物及其研究意義簡介 .................................................................................................1 配合物的研究現(xiàn)狀 .....................................................................................................................2 鄰菲啰啉配合物的研究現(xiàn)狀 .....................................................................................................4 對 1,10鄰菲啰啉配合物的研究 .........................................................................................4 1,10鄰菲啰啉作為第二配體的配合物的研究 ..................................................................5 關(guān)于 1,10鄰菲啰啉衍生物的配合物的工作 ....................................................................6 芳香羧酸配合物的結(jié)構(gòu) .............................................................................................................6 銅芳香羧酸配合物 .....................................................................................................................6 銅芳香羧酸配合物的合成 .........................................................................................................7 常規(guī)溶液反應(yīng)法 ..................................................................................................................7 水熱法 ..................................................................................................................................7 溶膠凝膠法 ........................................................................................................................7 流變相反應(yīng)法 .....................................................................................................................8 論文的立題依據(jù)及研究方案 .....................................................................................................8第二章 由對苯二甲酸構(gòu)筑的銅的配位聚合物的水熱合成及晶體結(jié)構(gòu) .........................................9 引言 .............................................................................................................................................9 實驗方法 .....................................................................................................................................9 藥品和試劑 ..........................................................................................................................9 儀器和設(shè)備 .........................................................................................................................9 實驗步驟 ...........................................................................................................................10 晶體結(jié)構(gòu)的測定及討論 ...........................................................................................................11 晶體結(jié)構(gòu)的測定 ...............................................................................................................11 晶體結(jié)構(gòu)及討論 ................................................................................................................13 熱失重的研究 ...........................................................................................................................14第三章 結(jié)論 .......................................................................................................................................15致謝 .....................................................................................................................................................16參考文獻 .............................................................................................................................................17江蘇大學(xué)本科畢業(yè)論文—II—由對苯二甲酸構(gòu)筑的銅的配位聚合物的水熱合成及晶體結(jié)構(gòu)摘要：采用水熱法合成了一種新型配位聚合物[Cu(MOPIP)(BDC)] n(H2O) ( MOPIP = 2 – ( 4 甲氧基)1H 咪唑[ 4,5 氟] [ 1,10 ] 鄰菲羅