【正文】 ，反應溫度 65℃。 第三、 在此基礎上通過 BoxBehnken 法設計出 13 組實驗得出該工藝的最優(yōu)工藝參數(shù)為： 醇油比為 :1，催化劑用量為 4wt%，反應溫度為 ℃ ，反應時間為 60min。 關鍵詞 ： 生物柴油 , 籽油，固體堿催化劑， BoxBehnken 法 IX BIODIESEL PRODUCTION FROM ENERGYTREE SEED OIL ABSTRACT As environmental issues and energy issues became serious, the development of renewable energy has attracted more and more attention by present researcher. Biodiesel is one of the alternatives to petroleum fuel and it can be produced through transesterification of vegetable oil, animal fats and recycle greases with methanol in the presence of a catalyst. The main ponent of biodiesel is fatty acid methyl esters. Biodiesel has many advantages: low viscosity, high flash point, high cetane number, nontoxic and biodegradable, and it can reduce greenhouse gases release to the atmosphere during the utilization. It is of a great significance for solving the global warming problem and reduction of acid rain, protecting environment and achieving sustainable economic development. In this study, seed oil was used as the feedstock. The main subject of this study is divided into three parts: The first, the parameters of the production of biodiesel was settled as below: the molar ratios of methanol to oil is in the range of 4: 1 ~ 12:1, quantity of acid catalyst is in the range of 4wt% ~ 12wt%, reaction temperature is in the range of 60℃ ~ 80℃ and reaction time ranges from 90min ~ 180min. The second, 13 experiments were designed by the single factor method to determine the optimal parameters. After 180min reaction, acid values of reacted mixture were detected and the results showed that the optimal conditions of biodiesel production are: molar ratios of methanol to oil, 9:1。 loaded acid catalyst, 6wt%。 reaction temperature, 65℃ . The last, based on the above results, 13 experiments were obtained by BOXBehnken design and results showed that the the optimal conditions of biodiesel production are: molar ratios of methanol to oil, :1。 loaded acid catalyst, 4wt%。 reaction temperature, ℃ 。 reaction time, 60min. X KEY WORDS: biodiesel, seed oil, solid base catalyst, esterification, BoxBehnken design XI 目 錄 前 言 ................................................................................................. 13 第一章 綜 述 ................................................................................. 14 167。 生物柴油的概述 ..................................... 14 167。 動植物油脂的化學結構以及生物柴油的組成 ............ 15 167。 動植物油脂的化學結構 [8 ] ............................................................................. 15 167。 生物柴油的組成 ............................................................................................. 16 167。 生物柴油與石化柴油的的比較 [10]............................................................... 17 167。 生物柴油的生產(chǎn)方法 ................................. 18 167。 均相催化法 ...................................................................................................... 19 167。 非均相催化法 .................................................................................................. 20 167。 生物催化法 ...................................................................................................... 21 167。 超臨界法 .......................................................................................................... 22 167。 不同生產(chǎn)方法的比較 ..................................................................................... 23 167。 我國發(fā)展生物柴油的現(xiàn)狀以及意義 ..................... 24 167。 國內(nèi)的油料作物資源以及分布 .................................................................... 24 167。 國內(nèi)的生物柴油的發(fā)展 ................................................................................. 25 167。 本課題研究目的及方案 ............................... 26 第一章 實驗部分 ........................................ 錯誤 !未定義書簽。 167。 實驗目的及內(nèi)容 ...................... 錯誤 !未定義書簽。 167。 實驗目的 ........................................................................... 錯誤 !未定義書簽。 167。 實驗內(nèi)容 ........................................................................... 錯誤 !未定義書簽。 167。 實驗原料以及儀器 .................... 錯誤 !未定義書簽。 167。 實驗原料 ........................................................................... 錯誤 !未定義書簽。 167。 實驗試劑 ........................................................................... 錯誤 !未定義書簽。 XII 167。 實驗儀器 ........................................................................... 錯誤 !未定義書簽。 167。 實驗裝置 ............................ 錯誤 !未定義書簽。 167