氰基橋聯(lián)配合物的磁性研究(參考版)
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【正文】 2CH3OH(3) have been studied，It is showed that there is respectively a ferromagic interaction interaction between neighboring metal ions in all of bestfit leads to the parameters g = ，J = for plex 1 and g = ，J = for plex ，the value of J for plex 3 has been investigated.[keywords] Cyanobridged plexes magic susceptibilities magic interactions crystal structure。3H2O(1)、[{FeⅢ (dpq)(CN)4}2CuⅡ ]zec, J. Pasa, C. R. Perez, J. Vaissermann, J. Cano, R. Carrasco, W. Wernsdorfer, F. Lloret, and M. Julve, [Fe(bpym)(CN)4], A New Building Block for Designing SingleChain Mags, Chen. Soc., 2022，4842~4853.[19]Kahn O ,Briat B. Exchange interaciton in polynuclear plexe Part 1. Principles,model and application to the binuclear plexes of chromium (Ⅲ)[J ]. J Chem Soc Faraday T rans, 1976，72268~281鹽城師范學院畢業(yè)論文（設(shè)計）20[20]Girerd J J , Journeaux Y, Kahn O. Natural or orthogonalized magic orbitals: two alternative ways to describe the exchange interaction[J ]. Chem Phys L et t, 1981，82：534~538[21] Luminita ., Rodrigue L., Je P., Catalina ., Jacqueline V., Joan Cano,Rosa C., Wollfgane W., Francefc L.,and Miguel J. [Fe (bpym)(CN)4]: A New Building Block for Designing SingleChain Mags. ., 2022，128：4842~4853.[22] HeRui Wen, CaiFeng Wang, You Song, YiZhi Li, JingLin Zuo, XiaoZeng You. Syntheses, structures, and magic properties of heterobimetallic plexes based on tetracyanometallic building block[J]. Inanica Chimica Acta, 2022，361：2901~2908.Magic properties of Cyanobridged plexesZhong Chao[Abstract] Cyanobridged plexes have caused great attention due to their versatile bridging in the field of molecular mags，the intriguing magic properties and structures have attracted extensive interest. The variabletemperature magic susceptibilities for singlemolecular mag [{FeⅢ (Mephen)(CN)4}2CoⅡ (H2O)4ezeca, L M. Tomaa, J. Vaissermann, M. Verdaguer, F. Delgado, Chem. Rev., 2022，249：2704~2714.[15]Wang CF, Zuo JL, Bartlett Bart M., et al. SymmetryBased Magic Anisotropy in the Trigonal Bipyramidal Cluster [Tp2(Me3ta)3Cu3Fe2(CN)6]4+[J]. ., 2022，128 (22)：7162 ~7163.[16]Rodrigue L，Jacqueline V，Luminita MT，et al. mer[FeIII(bpca)(CN)3]ˉ: A New LowSpin Iron(III) Complex to Build Heterometallic Ladderlike Chains[J]. In. Chem. 2022，43 (7)：234~235.[17]Luminita T.，Rodrigue L.，Jacqueline V.，et al. [CrIII(L)(CN)4]: a new building block in designing cyanidebridged 4,2ribbonlike chains{[CrIII(L) (CN)4]2 Mn(H2O)2}[參考文獻][1]于紅梅，戴衛(wèi)東，王壽武. 雜多核氰根橋聯(lián)配合物的研究進展. 河北理工學報，2022， 26(1)：112~115.[4]孟笑天，李永利，李保 衛(wèi). 單分子磁體的研究 進展. 生物磁學， 2022，6(1)：61~65. [5]王天維， 林小駒，韋吉宗，黃輝，游效曾 . 單分子磁體. 無機化學學 報，2022，18：1072~1079. [6]王慶倫， . 化學進展，2022，15 (3) ：162~169.[7]Caneschi A , Gatteschi D , Lalioti N , et al . Angew. Chem. Int. Ed. , 2022，40：1760~1763[8]許公峰， 王慶倫等. 單鏈磁體及其研究 進展﹒化學進展，2022，17(6)：970~976[9]王壽武， 李寶龍，朱霞，等 . 氰 根橋聯(lián)超分子配位化學研究進展[J]. 化學世界，2022，3：155156.[10]陶建清，王天維，顧志國，等. 基于[(Tp)Fe(CN) 3]
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