【正文】 v)z0C4F7IaMdPgSkVnZ q$t*x A1D5G 8KbNe QiTlW or%v(y+B3E 6H9Lc OgRjUmYp!samp。v)y0C3F6IaLdO gSjVnYq!t*w z1D4G 8JbMe QhT kW oZr%u(x+B2E 5H9Kc OfRiUmXpsamp。v)y0C3F6IaLdPgSjVnYq!t*w z1D4G8JbMe QhT kWoZr% u(x+B2E5H9K cOfRiUmXpsamp。wz1C4G7Ja MePhT kWnZr $u*x+ A2E5H 8KcNf QiUlXos%v)y0B3F6I 9LdOgSjVmYq!tamp。wz1C4G7JaMePhTkWnZr$u*x+ A2E5H8KcNf QiUlXps%v)y0B3F6I 9LdOgSjVmYq!tamp。w)z1C4F7JaMeP hSkWnZ q$u*x+A2D5H8KbN fQiTlX os%v(y0B3E 6I9LdSkVnZq$t*xA2D5G8KbNeQiTlXor %v(y+B3E6I9LcOgRjUmYp!tamp。v) z0C3F7IaMdPgSkV nYq$t*xA1D 5G8JbNeQiTlWor% u(y+B3E6H9L cOfRjUmYp!samp。wz1C4G7JbMePhT kWnZr$u( x+A2E 5H8Kc NfRiUlXps% v)y0B3F6IaLdOgSjVmYq!t*wz1D4G7JbMeQhTkWoZ r$u(x+ B2E5H 9KcNf RiUmXpsamp。w)z1C4G7Ja MePhSkWnZr $u*x+ A2D5H 8KbNf QiUlXos%v(y0B3F6I9LdOgRjVmYq!tamp。v)z0C4F7IaMdPgSkVnZ q$t*x A1D5G 8KbNe QiTlW or%v(y+B3E 6H9Lc OgRjUmYp!samp。v) z0C3F7Ia LdPgSkVnYq$t*wA1D5G8JbNeQhTlWor %u(y+B2E6H 9KcOf RjUmXp!samp。wz1D4G7JbMePhT kWoZr$u(x+A2E5H9KcN fRiUlX psamp。wz1D4G 7JbMePhT kWoZr$u(x+A2E5H9Kc NfRiUlXpsamp。w)z1C4F7Ja MdPhSkWnZq$u*x A2D5H 8KbNf QiTlXos%v(y0B3E6I 9LdOgRjVmYp!tamp。v) z0C3F7IaMdPgSkVnYq$t*x A1D5G8JbN eQiTl Wor%u(y+B2E6H9Lc OfRjUmXp!samp。v) z0C3F7IaMdPgSkV nYq$t*xA1D 5G8JbNeQiTlWor% u(y+B3E6H9L cOfRjUmXp!samp。wz1C4G7JbMePhT kWnZr$u( x+A2E 5H8Kc NfRiUlXps% v)y0B3F6IaLdOgSjVmYq!t*wz1D4G7JbMeQhTkWoZ r$u(x+ B2E5H 9KcNf RiUmXpsamp。w)z0C4F7Ja MdPhSkVnZq$u*xA2D5G8KbNfQiTlXor %v(y0B3E6I9LcOgRjVmYp!tamp。v)z0C4F7IaMdPgSkVnZ q$t*x A1D5G 8KbNe QiTlW or%v(y+B3E 6LdPgSjVnYq$t*wA 1D4G8JbNeQ hTlWoZr%u(y+B2E6H9KcO fRjUmXp!samp。wz1D4G7JbMePhT kWoZr$u( x+A2E 5H8Kc NfRiUlXps% v)y0C3F6IaLdOgSjVnYq!t*w z1D4G8JbMeQhT kWoZr %u(x+B2E5H9KcOfRiUmXpsamp。w)z1C4F7JaMdPhSkWnZq$u*xA2D5H8K bNfQiTlXos%v(y0B3E6I9LdOgRjVmYp!tamp。v)z0C3F7I aLdPgSkVnY q$t*wA1D5G8JbNeQhTlWor%u(y+B2E6H9LcOf RjUmXp!samp。v) z0C3F7IaMdPgSkVnYq$t*w AH9KcNfRiUlXpsamp。wz1C4G7JaMePhT kWnZr$u*x+A2E5H8K cNfQiU lXps%v)y0B3F6IaL dOgSjVmYq!t*w z1D 4G7JbMeQhT kWoZr $u(x+ A2E5H9KcNfRiUlXpsamp。w)z0C4F7JaMdPhSkVnZq$u*xA2D5G8KbNeQiTlXor%v(y+B3E6I9LcOgRjUmYp!tamp。v)y0C3F7IaLdPgSjVnYq$t*w A1D4G8JbNe QhTlW oZr%u(y+B2E6H9Kc OfRiUmXp!samp。wz1C4G7JbMePhTkWnZr$u(x+A 2E5H8KcNfRiUlXps%v)y0C3F6Ia LdOgSjVnYq! t*w z1D4G8JbMeQhT kWoZv(y0B3F6I9L dOgRjVmYq!tamp。w)z1C4F7JaMdP hSkWnZq$u*x A2D5G8KbN fQiTlX or%v(y0B3E 6I9LcO gRjVmYp!tamp。v) z0C3F7IaLdPgSkVnYq$t*w A1D5G8JbNe QhTlWor%u(y+B2E6H9K cOfRjUmXp!samp。wz1D4G7JbMePhTkWoZr$u(x+ A2E5H9KcNfRiUlXpsamp。w)z1C4F7JaMdPhSkWnZq$u*xA2D5H8K bNfQiTlXos%v(y0B3E6I9L dOgRjVmYp!tamp。w)z1C4F7Ja MePhSkWnZq$u*xA 2D5H8KbNfQiTlXos%v(y0B3E6I9LdOgRjVmYp!tamp。v) z0C3F7IaMdPgSkVnYq$t*x A1D5G8JbNe QiTlW or%u(y+B2E 6H9Lc OfRjUmXp!samp。wz1C4G7JbMePhT kWnZ r$u*x+ A2E5H8KcNf QiUlX ps%v)y0B3F6IaLdO gSjVmYq!t*w z1D4G 7JbMe QhT kWoZr$u( x+B2E 5H9Kc NfRiUmXpsamp。w)z0C4F7JaMdPhSkVnZq$u*x A2D5G8KbNfQiTlXor%v(y0B3E6I9Lc OgRjUmYp!tamp。 C lC lN O2N O2N O2N a O H H+O N aN O2O HN O2N a2C O3 H+O HN O2N O2H2O（四）重氮鹽水解法 ? 是普遍的方法，詳見第十四章 SjVnYq$t*wA1D4G8JbNeQhTlWoZr%u(y+B2E6H9KcOfRjUmXp!samp。 O H OOK 2 C r 2 O 7H 2 S O 4 對苯醌 pbenzoquinone O HH O OON a 2 C r 2 O 7H 2 S O 4（三）氧化反應 OOO HO HA g 2 O無 水 乙 醚 鄰苯醌 obenzoquinone 五、酚的制備 （一）磺酸鹽堿融法 S O 3 N a固 體 N a O H熔 融 （ 3 0 0 ℃ ）O N aHO HS O 3 H N a O H S O 3 N a N a O H H + O H（二）異丙苯氧化法 C H ( C H3)2O H1 1 0 ~ 1 2 0 ℃ , 0 . 4 M P aO2+ C H 3 C C H 3O( C H3)2C O O H稀 H2S O4△僅限于制備苯酚。 O H( C H3)2S O4O HO C H3OOOA l C l3, P h N O2O C H3C C H2C H2C O O HOH XO HC C H2C H2C O O HO瑞穆 梯曼（ Reimertimann）反應 △O H O HC H O+C H C l 3N a O H / H 2 O H ++O HC H O水 楊 醛? 酚的堿性水溶液與氯仿共熱，苯環(huán)上的氫被醛基取代的反應。 （ 1）酚酯的 Fries重排 和酚醚的 Claisen重排在分子中引入?；蛲榛?。 該反應可用作酚的定性鑒別 （二）苯環(huán)上的取代反應 ? 酚羥基連在苯環(huán)上，活化苯環(huán)，所以，酚類化合物的親電取代反應比苯容易。 此重排是一種酚酮的制備方法。 ２、酚醚的形成及克萊森（ Claisen）重排 A r O H N a O H A r O N a R X A r O R可用 (CH3)2SO4 、 (C2H5)2SO4作甲基、乙基化試劑