一維無(wú)限鏈狀配位聚合物三環(huán)己基錫鄰二茂鐵甲?；郊姿狨サ暮铣杀碚骷靶阅苎芯?資料下載頁(yè)
2025-06-23 16:24本頁(yè)面
【正文】 , 12: 32853295.[8] 蔡艷林. 含二茂鐵配合物的結(jié)構(gòu)及生物活性的研究[D]. 廣西: 廣西師范大學(xué), 2004. [9] 李偉. 二茂鐵苯甲酸類稀土配合物的合成、表征及性能研究[D]. 廣西: 廣西師范大學(xué), 2008.[10] 蔣伍玖. 大位阻烴基錫金屬有機(jī)化合物的合成、結(jié)構(gòu)和性質(zhì)研究[D]. 湘潭: 湘潭大學(xué), 2011.[11] 羅寧, 孫麗娟, 劉治中, 等. 三烴基錫二茂鐵甲酸酯的合成表征及其生物活性[J]. 應(yīng)用化學(xué), 2000, 17(2): 154158.[12] 柯以侃, 董慧茹. 分析化學(xué)手冊(cè): 第三分冊(cè)[M]. 北京: 化學(xué)工業(yè)出版社, 1998. 932935.[13] 萬(wàn)家亮, 曾勝年, 李俊義, 等. 分析化學(xué): 下冊(cè)[M]. 北京: 高等教育出版社, 2001. 182.[14] 鄺代治, 蔣伍玖, 馮泳蘭, 等. 三環(huán)己基錫吡啶酸甲酯的合成、結(jié)構(gòu)、熱穩(wěn)定性及其量子化學(xué)計(jì)算研究[J]. 無(wú)機(jī)化學(xué)報(bào), 2011, 27(10): 19821984.Synthesis, Characterization, Property of Tricyclohexyltin oFerrocencarbonylbenzoate OneDimenional Coordination PolymerApplied Chemistry student: WANG qinqin Tutor: YU jiangxiAbstract: Tricyclohexyltin oFerrocencarbonylbenzoate has been synthesized by the reaction of tricyclohexyltin hydroxide with oferrocencarbonylbenzoic acid in methanol. The structure was characterized by UV, IR, 1H NMR, 13C NMR, elemental analysis and Xray crystal diffraction. It′s crystal belongs to monoclinic system, space group P21/c, a = (2) nm, b = (3) nm, c = (4) nm, β = (10)176。, Z = 4, V = (11) nm3, Dc = Mgm3, m(MoKa)= mm1, F(000)= 1448, R1=, wR2 = . Crystal structure shows a distorted trigonal bipyramidal configuration with fivecoordination for the central tin atom. Due to the coordinations of the carboxyl and the carbonyl group, the 1D zigzag structure of the plex is formed. Moreover, the electrochemical performance, thermal stability and antitumour activity of the plex have been also studied.Key words: tricyclohexyltin carboxylate。 crystal structure。 electrochemical performance。 thermal stability。 antitumour activity
教學(xué)教案相關(guān)推薦
鄂ICP備17016276號(hào)-1