【正文】 第三節(jié) 球?qū)ΨQ性中原子軌道的特征標(biāo)精講文獻(xiàn)[65] Roger L. DeKock, Albion J. Kromminga, Timothy S. Zwier, “The symmetry of atomic states and atomic orbitals,” J. Chem. Educ. 56(8), 510511(1979)經(jīng)典文獻(xiàn)。第一節(jié) 光致變色材料研究 2學(xué)時第二節(jié) 熱致變色材料研究 2學(xué)時第三節(jié) 催化聚合材料研究 2學(xué)時[56]“Intermediate ion stability and regioselectivity in propene polymerization using neutral salicyladiminato nickel(II) and palladium(II) plexes as catalysts”，Yue Liu, Michael . Drew, Ying Liu，Journal of Molecular Structure: THEOCHEM, 2007, 809, 29 [57] “Ab Intio and Kinetic Study on CH3 Radical Reaction with H2CO”。 Lin, ShuWai J. Amer. Chem. Soc. 1979, 101, 56375649[35] Avnir, David, Chemically induced pulsations of interfaces: The mercury beating heart, Journal of Chemical Education, Volume 66 Number 3 March 1989:211When an iron needle just touches a mercury drop submerged in a pool of an acidic solution of an oxidizer, it pulsates rapidly in a mode that resembles a beating heart.[36] James L. Ealy, Jr, Gallium Beating Heart, Gallium Beating Heart, Journal of Chemical Education, Volume 70 Number 6 June 1993:491Oscillating gallium in a Petri dish offers an exciting demonstration (用Ga代替Hg)自學(xué)文獻(xiàn)[15] Martin Sanchez, M.。不同自旋的電子分別考慮。不同自旋的電子分別考慮，推求方法簡單。熱力學(xué)自學(xué)文獻(xiàn)[3] E. K. Mellon，An Apparent Contradiction in the Application of the Principle of Le Chatelier，JOURNAL OF CHEMICAL EDUCATION, Volume 56. Number 6. June 1979:380[4] Huang Xijun and Yan Xiuping, Influences of Temperature and Pressure on Chemical Equilibrium in Nonideal Systems, JOURNAL OF CHEMICAL EDUCATION, Volume 68 Number 4 April 1991:294[5] Theodros Solomon, The Temperature and Pressure Dependence of the Equilibrium Properties of a System, JOURNAL OF CHEMICAL EDUCATION, Volume 68 Number 4 April 1991:295[6] J. J. MacDonald，Equilibria and DG176。x, JOURNAL OF CHEMICAL EDUCATION, Volume 51, Number 9, September 1974:577[12] H. R. Kemp, The Effect of Temperature and Pressure on Equilibria: A Derivation of the van39。 一種純?nèi)苜|(zhì)（氣態(tài)或固態(tài)）和氣體飽和溶液成平衡的溶解平衡 對溶質(zhì)的平衡活度a2微分，有 c2為溶液中溶質(zhì)的濃度。式（385）和（384）要求反應(yīng)物和除產(chǎn)物p外的所有產(chǎn)物的初始摩爾數(shù)配比應(yīng)該分別等于反應(yīng)方程式中計量系數(shù)之比。當(dāng)時，隨著氮?dú)獾募尤?，Qp減小，平衡要向正反應(yīng)的方向移動，向增加氮?dú)獾姆较蛞苿樱cLe Chatelier原理的簡單表述結(jié)論相反。s Principle, A reexamination and method of graphic illustration，JOURNAL OF CHEMICAL EDUCATION,Volume 57, Number 6, June 1980:417該文獻(xiàn)從作圖斜率角度討論Le Chatelier and Braun原理，結(jié)果與精講文獻(xiàn)[1]一致。該文獻(xiàn)有一定深度，是一篇好文章。 要求：閱讀的文獻(xiàn)必須在一定程度上反映教學(xué)成就，要求有所收獲，按組給分。備用章節(jié)包含化學(xué)研究、基礎(chǔ)理論研究。每篇英文文獻(xiàn)是一個專業(yè)內(nèi)容，專業(yè)內(nèi)容可以用中文講授。本課程強(qiáng)調(diào)能力培養(yǎng)。在教師的幫助下讓學(xué)生通過英語學(xué)習(xí)沒有進(jìn)入教材的教學(xué)研究成果。講授內(nèi)容包含主要章節(jié)和備用章節(jié)兩個部分。本課程通過教學(xué)研究的英文文獻(xiàn)、多媒體教學(xué)手段講授較深入的專業(yè)知識。第一節(jié) 節(jié)面與原子核位置 2學(xué)時第二節(jié) 尖晶石與反式尖晶石的穩(wěn)定性 2學(xué)時第三節(jié) 球?qū)ΨQ性中原子軌道的特征標(biāo) 2學(xué)時第四節(jié) 位置對稱性與雜化軌道 2學(xué)時第五節(jié) 結(jié)構(gòu)化學(xué)課程相關(guān)基礎(chǔ)文獻(xiàn) 2學(xué)時撰寫人： 劉躍 審定人： 院（系）主管領(lǐng)導(dǎo)： 學(xué)院蓋章： 2006年7月9日二 教案第一章 化學(xué)平衡理論結(jié)合我們自己的工作,重點講授加入一種物質(zhì),化學(xué)平衡向生成這種物質(zhì)的方向移動理論的英文文獻(xiàn)中文文獻(xiàn)導(dǎo)入 2學(xué)時[1] 劉躍,劉穎,楊小震,化學(xué)通報,2004,3,51[2] 劉躍,賀子如，劉穎,《平衡理論》，化學(xué)工業(yè)出版社，1995[3] 劉穎，劉躍《理論化學(xué)》，黑龍江科學(xué)技術(shù)出版社，2002英文文獻(xiàn)導(dǎo)讀 6學(xué)時, 在精講文獻(xiàn)中任選三篇文獻(xiàn)講解,每篇2學(xué)時.以下這些文獻(xiàn)的數(shù)學(xué)推導(dǎo)過程在《平衡理論》、《理論化學(xué)》、化學(xué)通報,2004,3,51中有詳細(xì)論述。同理，由式（220）可得 式（222）說明無論dP是正是負(fù)，平衡向增加壓強(qiáng)變化所產(chǎn)生的效果的方向移動，與Le Chatelier原理的簡單表述相矛盾。該文獻(xiàn)有一定深度，是一篇好文章。該文獻(xiàn)有一定深度，是一篇好文章。s Principle: The Effect of Temperature on the Solubility of Solids in Liquids, JOURNAL OF CHEMICAL EDUCATION, Volume 60 Number 5 May 1983:387詳細(xì)分析了應(yīng)用Le Chatelier原理分析溶解度隨溫度變化時出現(xiàn)的問題。飽和濃度處的微分熔解熱的正負(fù)號決定的符號。恒溫恒壓下有 G是體系的Gibbs自由能，是物質(zhì)j的化學(xué)勢，由式（8137）得 反應(yīng)過程中任意時刻，產(chǎn)物和反應(yīng)物的自由能的差值給出的值。 其中 （634）式表示N個方程，N個未知數(shù) 的方程組。p] could only be associated with the singlet. The antisymmetric direct product 3{p196。 Demiri, Sani，Mercury Beating Heart: Modifications to the Classical Demonstration，Journal of Chemical Education, Journal of Chemical Education, Vol. 84 No. 8 August 2007:1292采用電極代替鐵釘，在NaOH溶液中汞心臟也能挑動。 Draeger, J. A The kinetics of oscillating reactions: Laboratory experiment for physical chemistry , Journal of Chemical Education, Volume 69 Number 7 July 1992:596 This experiment presents chemical dynamic relationships and promotes the use of puters for analysis. (振蕩反應(yīng)可以用偏微分方程的類周期解來模擬)自學(xué)文獻(xiàn)[16] John A. Pojman and William W. West, A Unified Physical Chemistry Laboratory Based on Oscillating Reactions and Traveling Fronts，Journal of Chemical Education, January, 1996, Vol. 73 No. 1:35第三節(jié)Blue Bottle 藍(lán)瓶反應(yīng)[39] J. A. Campbell, KineticsEarly and Often, Journal of Chemical Education, Volume 40, Number 11, November 1963:579[40] A. Gilbert Cook, Randi l ive, Janelle E. Williarns, The Blue Bottle Experiment Revisited, Journal of Chemical Education, 1994, Vol. 71 No. 2:160[41] Walter R. Vandaveer, et al. The Blue Bottle Revisited, Journal of Chemical Education, Vol. 74 No. 4 April 1997: 402[42] Whitney E. Wellman, Mark E. Noble, Tom Healy, Greening the Blue Bottle, Journal of Chemical Education, Vol. 80 No. 5 May 2003:537第四節(jié)Memory Metal 記憶反應(yīng)精講文獻(xiàn)[43] Gisser, Kathleen R. C. et al Memory Metal: A Smart Material Exhibiting a SolidState Phase Change and Superelasticity, Journal of Chemical Education, January, Volume 71 Number 4 April 1994:335Several simple experiments that illustrate the shapememory, mechanical, and acoustical properties of Nitinol. (馬氏體與奧氏體)[44] JCE Editorial Staff，Memory Metal， Journal of Chemical Education， Vol. 82 No. 10 October 2005：1488AIn this Activity, students investigate the properties of wire made from nitinol metal and pare its properties to wire made from other metals such as copper and galvanized steel. Using the observed properties of nitinol metal, students then design (and may make) a toy that would use nitinol metal to operate. 自學(xué)文獻(xiàn)[17] George B. Kauffman，Isaac Mayo, The Thermobile?: A NitinolBased Scientific Toy, Journal of Chemical Education, Vol.