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氰基橋聯(lián)配合物的磁性研究(文件)

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【正文】 . 20 Chain structure views of 3 showing the atomlabeling scheme.鹽城師范學(xué)院畢業(yè)論文(設(shè)計(jì))17圖 21 化合物 3 的 ΧMT 對溫度 T 的變化曲線Fig. 21 Temperature dependence of the ΧMT product for 3 in the temperature range 0300 solid lines represent the best fits with △ positive.圖 22 配合物[Cu Ⅱ (bpca)FeⅢ (4, 439。?dmbipy)2(CN) 8]n.圖24 [CuⅡ (CH3OH)2FeⅢ 2(4, 439。但配合物 3 離子耦合磁交換未能擬合出,其主要因素在于鹽城師范學(xué)院畢業(yè)論文(設(shè)計(jì))19沒有查閱到相關(guān)模型公式或者未能根據(jù)類似配合物演算出理想公式,還有待于進(jìn)一步的研究。[參考文獻(xiàn)][1]于紅梅,戴衛(wèi)東,王壽武. 雜多核氰根橋聯(lián)配合物的研究進(jìn)展. 河北理工學(xué)報(bào),2022, 26(1):112~115.[4]孟笑天,李永利,李保 衛(wèi). 單分子磁體的研究 進(jìn)展. 生物磁學(xué), 2022,6(1):61~65. [5]王天維, 林小駒,韋吉宗,黃輝,游效曾 . 單分子磁體. 無機(jī)化學(xué)學(xué) 報(bào),2022,18:1072~1079.  [6]王慶倫, . 化學(xué)進(jìn)展,2022,15 (3) :162~169.[7]Caneschi A , Gatteschi D , Lalioti N , et al . Angew. Chem. Int. Ed. , 2022,40:1760~1763[8]許公峰, 王慶倫等. 單鏈磁體及其研究 進(jìn)展﹒化學(xué)進(jìn)展,2022,17(6):970~976[9]王壽武, 李寶龍,朱霞,等 . 氰 根橋聯(lián)超分子配位化學(xué)研究進(jìn)展[J]. 化學(xué)世界,2022,3:155156.[10]陶建清,王天維,顧志國,等. 基于[(Tp)Fe(CN) 3]?氰基橋聯(lián)雙核配合物的合成、結(jié)構(gòu)和磁性研究[J]. 無機(jī)化學(xué)學(xué)報(bào), 2022,22(12):2207~2211.[11]袁愛華,周虎,沈小平. 氰基橋聯(lián) 配合物的研究進(jìn)展[J]. 化學(xué)研究與應(yīng)用,2022,63:582~583.[12]OhbaM Okawa H. Coordination Chemistry Reviews, 200,198:313 ~328 .[13] Ni ZH, Kou HZ, Zhang LF,et al. [MnIII(salen)]6[FeIII(bpmb)(CN)2]6zec, J. Pasa, C. R. Perez, J. Vaissermann, J. Cano, R. Carrasco, W. Wernsdorfer, F. Lloret, and M. Julve, [Fe(bpym)(CN)4], A New Building Block for Designing SingleChain Mags, Chen. Soc., 2022,4842~4853.[19]Kahn O ,Briat B. Exchange interaciton in polynuclear plexe Part 1. Principles,model and application to the binuclear plexes of chromium (Ⅲ)[J ]. J Chem Soc Faraday T rans, 1976,72268~281鹽城師范學(xué)院畢業(yè)論文(設(shè)計(jì))20[20]Girerd J J , Journeaux Y, Kahn O. Natural or orthogonalized magic orbitals: two alternative ways to describe the exchange interaction[J ]. Chem Phys L et t, 1981,82:534~538[21] Luminita ., Rodrigue L., Je P., Catalina ., Jacqueline V., Joan Cano,Rosa C., Wollfgane W., Francefc L.,and Miguel J. [Fe (bpym)(CN)4]: A New Building Block for Designing SingleChain Mags. ., 2022,128:4842~4853.[22] HeRui Wen, CaiFeng Wang, You Song, YiZhi Li, JingLin Zuo, XiaoZeng You. Syntheses, structures, and magic properties of heterobimetallic plexes based on tetracyanometallic building block[J]. Inanica Chimica Acta, 2022,361:2901~2908.Magic properties of Cyanobridged plexesZhong Chao[Abstract] Cyanobridged plexes have caused great attention due to their versatile bridging in the field of molecular mags,the intriguing magic properties and structures have attracted extensive interest. The variabletemperature magic susceptibilities for singlemolecular mag [{FeⅢ (Mephen)(CN)4}2CoⅡ (H2O)42CH3OH(3) have been studied,It is showed that there is respectively a ferromagic interaction interaction between neighboring metal ions in all of bestfit leads to the parameters g = ,J = for plex 1 and g = ,J = for plex ,the value of J for plex 3 has been investigated.[keywords] Cyanobridged plexes magic susceptibilities
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