【正文】 XXX 大學(xué)工程碩士專業(yè)學(xué)位論文 論文題目： 凝結(jié)水精制技術(shù)的應(yīng)用研究 碩 士 生： 指導(dǎo)教師： 教授 工程領(lǐng)域： 化學(xué)工程 2022 年 6 月 9 日Thesis for the Graduate Candidate TestResearch on application and purification technology for condensed waterCandidate: Ma Haifeng Tutor: Wang Jian Field: Chemical EngineeringDate of oral examination: June 9th, 2022University: Northeast Petroleum University東北石油大學(xué)工程碩士專業(yè)學(xué)位論文I學(xué)位論文獨(dú)創(chuàng)性聲明本人所呈交的學(xué)位論文是我在指導(dǎo)教師的指導(dǎo)下進(jìn)行的研究工作及取得的研究成果。據(jù)我所知，除文中已經(jīng)注明引用的內(nèi)容外，本論文不包含其他個(gè)人已經(jīng)發(fā)表或撰寫過的研究成果。對(duì)本文的研究做出重要貢獻(xiàn)的個(gè)人和集體，均已在文中作了明確說明并表示謝意。 作者簽名： 日期： 學(xué)位論文使用授權(quán)聲明本人完全了解 XXX 大學(xué)有關(guān)保留、使用學(xué)位論文的規(guī)定。學(xué)校有權(quán)保留學(xué)位論文并向國家主管部門或其指定機(jī)構(gòu)送交論文的電子版和紙質(zhì)版，允許論文被查閱和借閱，可以采用影印、縮印或掃描等復(fù)制手段保存、匯編學(xué)位論文，可以公布論文的全部或部分內(nèi)容。XXX 大學(xué)有權(quán)將本人的學(xué)位論文加入 《 中國優(yōu)秀碩士學(xué)位論文全文數(shù)據(jù)庫》 、《中國博士學(xué)位論文全文數(shù)據(jù)庫》和編入《中國知識(shí)資源總庫》 。保密的學(xué)位論文在解密后適用本規(guī)定。學(xué)位論文作者簽名： 導(dǎo)師簽名： 日期： 日期：東北石油大學(xué)工程碩士專業(yè)學(xué)位論文II凝結(jié)水精制技術(shù)的應(yīng)用研究摘 要本課題是緊密結(jié)合大慶石化化工區(qū)乙烯裝置凝結(jié)水實(shí)際現(xiàn)狀提出的，通過乙烯裝置工藝凝結(jié)水現(xiàn)狀進(jìn)行調(diào)查和水質(zhì)分析，調(diào)研凝結(jié)水精制出水水質(zhì)要求，同時(shí)考察凝結(jié)水處理工藝和方法，擬通過實(shí)驗(yàn)考察凝結(jié)水阻截除油應(yīng)用工藝效果，提出凝結(jié)水精制優(yōu)化方法。 大慶石化乙烯裝置的凝結(jié)水比煉油裝置復(fù)雜很多，在換熱器等設(shè)備泄漏情況下，可能含有硫氰酸鈉、丙烯、氨、氫氰酸、苯、丁二烯、溶劑油、丁烯、氮?dú)?、乙烯、鐵、鈣離子、鎂離子、氯根、硫酸根、磷酸根等污染物質(zhì)，對(duì)凝結(jié)水的水質(zhì)影響較大，且難以處理。大慶石化原有凝結(jié)水精制裝置采用精密過濾器、焦炭過濾器處理、混床工藝處理，原設(shè)計(jì)經(jīng)除油及其它雜質(zhì)后，應(yīng)用于脫鹽水的設(shè)備，但由于當(dāng)時(shí)除油技術(shù)的局限性，水質(zhì)達(dá)不到所需要求（含油小于 ） ，因此一直沒有應(yīng)用，送入循環(huán)水場作為循環(huán)補(bǔ)充水。因此，本試驗(yàn)通過對(duì)化工凝結(jié)水進(jìn)行污染物種類、成分濃度進(jìn)行比對(duì)分析，選用兩級(jí)預(yù)屏障工藝和三級(jí)阻截除油工藝與覆蓋過濾器和活性碳過濾器處理工藝對(duì)進(jìn)行中試實(shí)驗(yàn)，通過連續(xù)監(jiān)測各個(gè)組合工藝日平均出水指標(biāo)，找出處理效果變化趨勢，結(jié)果證明兩級(jí)預(yù)屏障工藝和三級(jí)阻截除油工藝的組合工藝更能有效降低凝結(jié)水的油和離子含量，化工凝結(jié)水經(jīng)過處理后，出水油≤，去除率達(dá)%， COD≤ mg/L，經(jīng)過混床處理后，出水能夠達(dá)到中石油規(guī)定的鍋爐給水標(biāo)準(zhǔn)且運(yùn)行成本相對(duì)低廉，具有可觀的經(jīng)濟(jì)效益和環(huán)境效益。實(shí)驗(yàn)表明兩級(jí)預(yù)屏障工藝和三級(jí)阻截除油工藝組合工藝對(duì)化工區(qū)乙烯裝置凝結(jié)水具有較好的處理效果。關(guān)鍵詞：凝結(jié)水，油去除率，電導(dǎo)去除率，阻截除油 東北石油大學(xué)工程碩士專業(yè)學(xué)位論文IIIResearch on application and purification technology for condensed waterABSTRACTThis topic is in close connection with the Daqing Petrochemical chemical ethylene plant in the actual status of the condensate through the ethylene plant process condensate situation survey and water quality analysis, research condensate refining water quality requirements also investigated the condensation of water treatment processes and methods, the proposed condensate interception degreasing process effect, the experiment investigated proposed condensate refined optimization method.Petrochemical ethylene plant in Daqing condensate refining unit plex, the leakage of heat exchangers and other equipment, may contain sodium thiocyanate, propylene, ammonia, hydrogen cyanide, benzene, butadiene, solvents, oil, butylene, nitrogen, ethylene, iron, alcium, magnesium, chloride, sulfate, phosphate and other pollutants, water quality impacts of the condensate and difficult to handle. Daqing Petrochemical original condensate refining unit with precision filter, coke filter processing, the mixed bed process, the original design after oil and other impurities used in the equipment of the desalinated water, but because degreasing technology limitations, water quality to reach the necessary requirements (oil is less than / L), has not been applied, add water into the circulating water field as a circular. Therefore, the test by chemical condensate types of pollutants, ingredient concentration than the analysis, the choice of two prebarrier process and three intercept degreasing process and cover the filter and activated carbon filter treatment process of pilot test through continuous monitoring of various binations of process average effluent indicators to identify the treatment effect trend, results show that the bination of two prebarrier process and three intercept degreasing process technology more effectively to reduce the oil and ion content of the condensate, chemical condensation water after treatment, the effluent oil≤ / L, the removal rate of % of COD≤ mg / L, after a mixed bed, the water can reach the oil requirements of the boiler feed water standards and relatively low running costs, with considerable economic benefits and environmental benefits. The experiments show that the two prebarrier process and three intercept degreasing processes bined process chemical ethylene plant in the condensate has a better treatment effect.Key words：Condensate。 Oil removal 。 Conductivity removal；Interdiction degreasing東北石油大學(xué)工程碩士專業(yè)學(xué)位論文IV創(chuàng)新點(diǎn)摘要本文主要研究的是化工區(qū)乙烯裝置凝結(jié)水一種新型的處理工藝，其創(chuàng)新點(diǎn)如下：1．本文通過現(xiàn)場同步試驗(yàn)，測定兩種不同工藝組合對(duì)化工區(qū)乙烯裝置凝結(jié)水處理的效果，并檢驗(yàn)了阻截除油工藝的運(yùn)行穩(wěn)定性和抗沖擊性，極具推廣應(yīng)用價(jià)值。2．利用兩級(jí)預(yù)屏障工藝和三級(jí)阻截除油工藝組合工藝，能夠?qū)⒒^(qū)乙烯裝置凝結(jié)水的出水油在 ，去除率達(dá) %左右， COD≤ mg/L，達(dá)到中石油規(guī)定的鍋爐給水標(biāo)準(zhǔn)驗(yàn)證了兩級(jí)預(yù)屏障工藝+三級(jí)阻截除油工藝+活性炭+ 混床組合工藝適用于化工區(qū)乙烯裝置凝結(jié)水處理。3．兩級(jí)預(yù)屏障工藝+三級(jí)阻截除油工藝+ 活性炭+混床組合工藝，在處理總鐵、油、電導(dǎo)等低濃度化工區(qū)乙烯裝置凝結(jié)水中，運(yùn)行成本低廉，性能穩(wěn)定。東北石油大學(xué)工程碩士專業(yè)學(xué)位論文目 錄學(xué)位論文獨(dú)創(chuàng)性聲明 .................................................................................................................I學(xué)位論文使用授權(quán)聲明 .............................................................................................................I摘 要 ......................................................................................................................................IIABSTRACT..............................................................................................................................III創(chuàng)新點(diǎn)摘要 ..............................................................................................................................IV前 言.......................................................................................................................................1第一章 文獻(xiàn)綜述.......................................................................................................................3 凝結(jié)水處理現(xiàn)狀 .........................................................................................................................3 凝結(jié)水處理的特點(diǎn) .....................................................................................................................3 凝結(jié)水除油除鐵技術(shù) ........................................................