【正文】 西北師范大學(xué)化學(xué)化工學(xué)院 College of Chemistry and Chemical Engineering, Northwest Normal University 第十章 醇 酚 醚 西北師范大學(xué)化學(xué)化工學(xué)院 College of Chemistry and Chemical Engineering, Northwest Normal University 1. 寫(xiě)出戊醇 C5H11OH異構(gòu)體的構(gòu)造式，并用系統(tǒng)命名法命名。 C H 3 H 2 C H 2 C H 2 C H 2 O H C H 3 C H 2 C H 2 C H C H 3O HC H 3 C H 2 C H C H 2 C H 3O HC H 3 C H 2 C H C H 2 O HC H 3C H 3 C H C H 2 C H 2 O HC H 3C H 3 C H 2 C C H 3C H 3O HC H 3 C H C H C H 3O HC H 3C H 3 C C H 2 O HC H 3C H 31. 戊醇的異構(gòu)體如下： 1戊醇 2戊醇 (一對(duì)對(duì)映體 ) 3戊醇 2甲基 1丁醇 (一對(duì)對(duì)映體 ) 2甲基 2丁醇 3甲基 1丁醇 3甲基 2丁醇 (一對(duì)對(duì)映體 ) 2,2二甲基 1丙醇 西北師范大學(xué)化學(xué)化工學(xué)院 College of Chemistry and Chemical Engineering, Northwest Normal University ： C CC H 3 HH C H 2 C H O H C H 3C H 3 C H 2 C H C H C H 3C H 3 O O HC l C H 2 C H 2 O HHCH 3C2H5OHC 2 H 5 O C H 2 C H ( C H 3 ) 2O HO HC lO2 NB r O C 2 H 5B rO H( C H 3 ) 2 C HB rCH2OCH3CHOCH3CH2OCH3C H 2 C H C H 2 C H 3O(1) (2) (3) (4) (5) (6) (7) (8) (9) (10) 西北師范大學(xué)化學(xué)化工學(xué)院 College of Chemistry and Chemical Engineering, Northwest Normal University (1) 3甲氧基 2戊醇 (2) (E)4己烯 2醇 (3) 2對(duì)氯苯基乙醇 (4) (1S, 2R)2甲基 1乙基環(huán)己醇 (5) 2甲基 1乙氧基丙烷 (6) 3氯 4硝基鄰苯二酚 (7) 4溴苯乙醚 (8) 4異丙基 2,6二溴苯酚 (9) 1,2,3三甲氧基丙烷 (10) 1,2環(huán)氧丁烷 2. 西北師范大學(xué)化學(xué)化工學(xué)院 College of Chemistry and Chemical Engineering, Northwest Normal University 寫(xiě)出下列化合物的構(gòu)造式： (1) (E)2丁烯 1醇 (2) 烯丙基正丁醚 (3) 對(duì)硝基芐甲醚 (4) 鄰甲氧基苯甲醚 (5) 2,3二甲氧基丁烷 (6) α,β二苯基乙醇 (7) 新戊醇 (8) 苦味酸 (9) 2,3環(huán)氧戊烷 (10) 15冠 5 3. 西北師范大學(xué)化學(xué)化工學(xué)院 College of Chemistry and Chemical Engineering, Northwest Normal University ( 1 )3 . C CH 3 CHHC H 2 O H( 2 ) H 2 C C H C H 2 O C H 2 C H 2 C H 3 O 2 N C H 2 O C H 3( 3 )( 4 )O C H 3O C H 3( 5 ) C H 3 C H C H C H 3O C H 3 O C H 3( 6 ) C H 2 C HO H( 1 0 )O OOOO( 7 ) H 3 C CC H 3C H 3C H 2 O H ( 8 )O HN O 2N O 2O 2 NC H 3 C H C H C H 2 C H 3O( 9 )西北師范大學(xué)化學(xué)化工學(xué)院 College of Chemistry and Chemical Engineering, Northwest Normal University 4. 寫(xiě)出下列化合物的構(gòu)造式： (1) 2,4dimethyl1hexanol (2) 4penten2ol (3) 3bromo4methylphenol (4) 5nitro2naphthol (5) tertbutyl phenyl ether (6) 1,2dimethoxyethane 西北師范大學(xué)化學(xué)化工學(xué)院 College of Chemistry and Chemical Engineering, Northwest Normal University 4 . ( 1 ) C H 3 C H 2 C H C H 2 C H C H 2 O HC H 3 C H 3( 2 ) C H 2 C H C H 2 C H C H 3O H( 3 ) H3 C O HB r( 4 )O HN O 2( 5 ) CH 3 CC H 3C H 3O ( 6 )C H 2 C H 2O C H 3 O C H 3西北師范大學(xué)化學(xué)化工學(xué)院 College of Chemistry and Chemical Engineering, Northwest Normal University ： (1) Na (2) Al (3) 冷濃 H2SO4 (4) H2SO4 ,160℃ (5) H2SO4 ,140℃ (6) NaBr + H2SO4 (7) 紅磷＋碘 (8) SOCl2 (9) CH3C6H4SO2Cl (10) (1)的產(chǎn)物＋ C2H5Br (11) (1)的產(chǎn)物＋叔丁基氯 (12) (5)的產(chǎn)物＋ HI(過(guò)量 ) 西北師范大學(xué)化學(xué)化工學(xué)院 College of Chemistry and Chemical Engineering, Northwest Normal University ( 5 ) C H 3 C H C H 3O H+ H 2 S O 4 ( 濃 ) 1 4 0 ℃ C H 3 C HC H 3O C HC H 3C H 3C H 3 C H C H 3O H( 6 ) N a B r + H 2 S O 4+ C H 3 C H C H 3B rC H 3 C H C H 3O H5 . ( 1 ) N a C H 3 C H C H 3O N aC H 3 C H C H 3O H( 2 ) A l [ ( C H 3 ) 2 C H O ] 3 A l( 3 ) C H 3 C H C H 3O H+ H 2 S O 4 ( 濃 ) 冷 C H 3 C H C H 3O S O 2 O H( 4 ) C H 3 C H C H 3O H+ H 2 S O 4 ( 濃 ) C H 3 C H C H 2 1 6 0 ℃西北師范大學(xué)化學(xué)化工學(xué)院 College of Chemistry and Chemical Engineering, Northwest Normal University ( 紅 )C H 3 C H C H 3O H( 7 ) I 2 + P+ C H 3 C H C H 3I( 8 ) C H 3 C H C H 3O H+ S O C l 2 C H 3 C H C H 3C l( 9 ) C H 3 C H C H 3O HH 3 C S O 2 C l+ C H 3 C HC H 3