【正文】
1ˊ二茂鐵二甲醛。 文獻(xiàn)調(diào)研乙合成的二茂鐵相關(guān)的二齒配體包括: A[3] [3] Vernon C. Gibson and Catherine M. Halliwell, Nicholas J. Long, Philip J. Oxford, Andrew M. Smith, Andrew J. P. White and David J. Williams.Dalton Trans , 2003 ,P918 – 926.B[4][4]Zhiqiang Weng, Shihui Teo,Lip Lin Kohband T. S. Andy Hor. Chem. Commun., 2006, 1319–1321 | 1319.[5] Jochen Niemeyer, Gerald Kehr, Roland Fr246。,1ˊ2,6二乙基苯胺二酰胺的合成 在裝有回流冷凝管的50 mL的圓底燒瓶中加入1g 1,1ˊ二茂鐵二乙酮,,1ˊ—2,6—,TLC跟蹤檢測(cè),展開(kāi)劑用石油醚/乙酸乙酯(體積比為3:1)反應(yīng)。條件分別為溶劑為無(wú)水乙醇或用金屬鈉干燥處理過(guò)甲苯和苯和催化劑為對(duì)甲基苯磺酸﹑四氯化鈦。二茂鐵1,1'2,6二甲基苯胺二酰胺 附近有吸收峰(C=N伸縮振動(dòng)),(CH伸縮振動(dòng)), cm1(茂環(huán)C=C伸縮振動(dòng)), cm1(CH彎曲振動(dòng)),, (苯環(huán)骨架伸縮振動(dòng))。結(jié)果實(shí)驗(yàn)沒(méi)有得到預(yù)計(jì)的產(chǎn)物。后過(guò)硅膠柱展開(kāi)劑用石油醚/乙酸乙酯(體積比為3:1)過(guò)柱。rg Eppinger, Katharina R. Nikolaides, Mei ZhangPresse,? Florian A. Riederer,Gerd W. Rabe, and Arnold L. Rheingold. Organometallics, , , 2008 737K[10] [10]華更紅上海交通大學(xué)碩士學(xué)位論文 新型手性二茂鐵配體的合成與應(yīng)用研究文獻(xiàn) [11]是羰基與苯胺類以碳氮單鍵配合[11] 林旭聰,謝增鴻,郭良洽,陳國(guó)南,合成化學(xué),2003,11(6):499502。關(guān)鍵詞:二茂鐵 合成 二甲酰基二茂鐵 配合物Graduate 2011, Faculty of Chemistry and Material Science ,Lang fang Teachers CollegeYang Xuewen and Tian ZhigangAbstract: In this experiment, ferrocene reactant, in the ferrocene cyclopentadienyl ring on the last two acetyl, and then obtained by sodium hypochlorite oxidation of 1,1ˊ ferrocene dicarboxylic acid, and then after esterification was 1,1ˊ Dimethyl ferrocene, and then lithium aluminum reduction obtained by the tetrahydro 1,1 dimethyl ferrocene, and then oxidized by the manganese dioxide was 1,1ˊ ferrocene aldehyde. After burning 1,1ˊ ferrocene aldehyde aniline as the ligand with four metal ions Coordination.朗讀顯示對(duì)應(yīng)的拉丁字符的拼音在應(yīng)用領(lǐng)域也有了很大的發(fā)展。7小時(shí)后有兩個(gè)點(diǎn),要下面的點(diǎn)。次氯酸鈉溶液濃度一定要濃度達(dá)到10%。在此,我對(duì)給予我無(wú)私幫助的肖老師表示萬(wàn)分的感謝!同時(shí)還感謝在實(shí)驗(yàn)過(guò)程中給予過(guò)我熱情幫助的老師和同學(xué)!1,1ˊ二茂鐵二乙酮 cm1 附近有吸收峰(C=O伸縮振動(dòng)), cm1附