【正文】
carbon electrodes:Estimating effective ion size in electrolytic solutions[J].J .Phys Chem B,2001,105(29) : 6880 6887[13] Mao L,Zhang K,Chan H S O,et al. Surfactantstabilized graphene/polyaniline nanofiber posites for high performance supercapacitor electrode[J].J. Mater. Chem.,2012,22(1):8085.[14] Xiang C,Li M,Zhi M,et al. Reduced graphene oxide/titanium dioxide posites for supercapacitor electrodes:Shape and coupling effects[J]. J. Mater. Chem.,2012,22(36):1916119167.[15] Ai W,Zhou W,Du Z,et al. Benzoxazole and benzimidazole heterocyclegrafted graphene for highperformance supercapacitor electrodes[J]. J. Mater. Chem.,2012,22(44):2343923446.[16] Ghosh S,An X,Shah R,et al. Effect of 1pyrene carboxylicacid functionalization of graphene on its capacitive energy storage[J]. J. Phys. Chem. C,2012,116(39):2068820693.[17] Gopalakrishnan K,Govindaraj A,Rao C N R. Extraordinary supercapacitor performance of heavily nitrogenated graphene oxide obtained by microwave synthesis[J]. J. Mater. Chem. A,2013,1(26):. 若不給自己設(shè)限,則人生中就沒有限制你發(fā)揮的藩籬。電極活性物的理論比電容能否在實際的超級電容器中發(fā)揮出來,還取決于電極活性材料在電化學(xué)超級電容器中的利用率。發(fā)展石墨烯基電極材料,有效減少石墨烯片層聚集和堆疊以獲得良好的體積比電容是構(gòu)建新型石墨烯基超級電容器的關(guān)鍵。電極材料作為決定超級電容器性能的最關(guān)鍵因素備受關(guān)注。但氮摻雜引起的比容量的增加機理仍有待進一步研究。利用尿素作為氮源,通過微波法合成了高氮含量的氧化石墨烯,其氮含量達(dá)到18%。Ghosh等[16]制備了1芘羧酸修飾的石墨烯,在6 mol/L的KOH水溶液中,其比電容達(dá)到200 F/g,遠(yuǎn)大于沒有修飾的石墨烯比電容(30 F/g)。Xiang等[14]制備了還原氧化石墨烯/TiO2納米帶和還原氧化石墨烯/TiO2納米粒子復(fù)合材料并作為超級電容器電極材料,當(dāng)還原氧化石墨烯與TiO2納米帶的用量比為7︰3時,其電化學(xué)性能最為優(yōu)異,以1 mol/L的Na2SO4水溶液作為電解質(zhì), A/g的電流密度下,其比容量達(dá)到225 F/g,比純還原氧化石墨烯、TiO2 和還原氧化石墨烯/TiO2納米粒子復(fù)合材料更高,且循環(huán)性能優(yōu)異。Mao等[13]在含有四丁基氫氧化銨或十二烷基苯磺酸鈉作為表面活性劑的溶液中原位聚合合成了石墨烯/聚苯胺納米纖維復(fù)合材