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【正文】 fur can severely reduce the hot workability of steels, because of the formation of iron sulfide, unless sufficient manganese is present to prevent such formation. At room temperature, the mechanical properties of resulfurized steels depend on the orientation of the deformed manganese sulfide inclusions (anisotropy). Rephosphorized steels are significantly less ductile, and are produced solely to improve machinability. Machinability of Various Other Metals Aluminum is generally very easy to machine, although the softer grades tend to form a builtup edge, resulting in poor surface finish. High cutting speeds, high rake angles, and high relief angles are remended. Wrought aluminum alloys with high silicon content and cast aluminum alloys may be abrasive。 this improves machinability. The size, shape, distribution, and concentration of these inclusions significantly influence machinability. Elements such as tellurium and selenium, which are both chemically similar to sulfur, act as inclusion modifiers in resulfurized steels. Phosphorus in steels has two major effects. It strengthens the ferrite, causing increased hardness. Harder steels result in better chip formation and surface finish. Note that soft steels can be difficult to machine, with builtup edge formation and poor surface finish. The second effect is that increased hardness causes the formation of short chips instead of continuous stringy ones, thereby improving machinability. Leaded Steels. A high percentage of lead in steels solidifies at the tip of manganese sulfide inclusions. In nonresulfurized grades of steel, lead takes the form of dispersed fine particles. Lead is insoluble in iron, copper, and aluminum and their alloys. Because of its low shear strength, therefore, lead acts as a solid lubricant (Section ) and is smeared over the toolchip interface during cutting. This behavior has been verified by the presence of high concentrations of lead on the toolside face of chips when machining leaded steels. When the temperature is sufficiently highfor instance, at high cutting speeds and feeds (Section )—the lead melts directly in front of the tool, acting as a liquid lubricant. In addition to this effect, lead lowers the shear stress in the primary shear zone, reducing cutting forces and power consumption. Lead can be used in every grade of steel, such as 10xx, 11xx, 12xx, 41xx, etc. Leaded steels are identified by the letter L between the second and third numerals (for example, 10L45). (Note that in stainless steels, similar use of the letter L means “l(fā)ow carbon,” a condition that improves their corrosion resistance.) However, because lead is a wellknown toxin and a pollutant, there are serious environmental concerns about its use in steels (estimated at 4500 tons of lead consumption every year in the production of steels). Consequently, there is a continuing trend toward eliminating the use of lead in steels (leadfree steels). Bismuth and tin are now being investigated as possible substitutes for lead in steels. CalciumDeoxidized Steels. An important development is calciumdeoxidized steels, in which oxide flakes of calcium silicates (CaSo) are formed. These flakes, in turn, reduce the strength of the secondary shear zone, decreasing toolchip interface and wear.
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