垃圾滲濾液溶解有機(jī)質(zhì)的紅外和熒光光譜比較研究(存儲(chǔ)版)
【正文】 solved anic matter in aquatic environments using a new approach to fluorescence spectroscopy [J]. Marine Chemistry, 2020, 82(34): 239254. [5] Wu F., Tanoue Eiichiro. Molecular mass distribution and fluorescence characteristics of dissolved anic ligands for copper (II) in Lake Biwa, Japan [J]. Organic Geochemistry, 2020, 32, (1): 1120. [6] Baker Andy. Fluorescence properties of some farm wastes implications for water quality monitoring [J]. Water Research, 2020, 36(1): 189195. [7] 郝瑞霞 ,曹可心 ,鄧亦文 . 城市污水處理過(guò)程中有機(jī)污染物三維熒光特性的變化規(guī)律 [J] . 分析測(cè)試學(xué)報(bào) , 2020,26(6):789～ 792. [8] 歐陽(yáng)二明 ,張錫輝 , 王偉 . 常規(guī)凈水工藝去除有機(jī)物效果的三維熒光光譜分析法 [J]. 光譜學(xué)與光譜分析 , 2020,27(7):1373～ 1376. [9] Yamashita Y,Tanoue E. Chemical characterization of proteinlike fluorophores in DOM in relation to aromatic amino acids[J]. Mar Chem, 2020, 82(34): 255~271. [10] 王麗莎 , 胡洪營(yíng) , 藤江幸一 . 污水氯和二氧化氯消毒過(guò)程中溶解性有機(jī)物變化的三維熒光光譜解析[J]. 環(huán)境科學(xué) , 2020, 28(7): 1524～ 1528. ： 垃圾滲濾 液溶解有機(jī)質(zhì)的紅外和熒光光譜比較研究 [11] Le Coupannec F,Morin D,Sire O, et al. Characterisation of dissolved anic matter (DOM) in landfill leachates using fluorescence excitation–emission matrix [J]. Environ Technol, 2020, 21(5): 515－ 524. [12] Baker Andy, Michael Curry. Fluorescence of leachates from three contrasting landfills [J]. Water Research, 2020, 38(10): 2605～ 2613. [13] 劉國(guó)強(qiáng) , 方芳 , 郭勁松 , 等 . 三峽庫(kù)區(qū)填埋場(chǎng)和焚燒廠滲濾液水質(zhì)季節(jié)性差異 [J]. 環(huán)境科學(xué)研究 . [14] Chen Y. Senesi N, Schnitzer M. 1977, Information provide on humic substances by E4/E6 ratios[J]. Soil Sci Soc Amj, 41: 352358. [15] Diane M. McKnight, Elizabeth W. Boyer, Paul K. Westerhoff, et al. Spectrofluorometric characterization of dissolved anic matter for indication of precursor anic material and aromaticity. Limnology and Oceanography, 2020, 46(1): 38–48. [16] 楊玉江 , 趙由才 . 生活垃圾填埋場(chǎng)垃圾腐殖質(zhì)組成和變化規(guī)律的表征 [J]. 環(huán)境科學(xué)學(xué)報(bào) ,2020,27(1):94. [17] McKnight D M, Boyer E W, Westerhoff P K et al, 2020. Spectrofluorometric characterization of dissolved anic matter for indication of precursor anic materials and aromaticity. Limnol Oceanogr, 46:3848. [18]Coble P G, Green S A, Blough N V et al, 1990. Characterization of dissolved anic matter in the Black Sea by fluorescence spectroscopy. Nature, 348: 432—435. [29] Coble P G, 1996. Characterization of marine and terrestrial DOM in seawater using excitationemission matrix spectroscopy. Mar Chem, 51: 325—346. [20] Mobed J J, Hemmingsen S L, Autry J L et al, 1996. Fluorescence characterization of IHSS humic substances:total luminescence spectra with absorbance correction. Environ Sci Technol, 30(10): 3061—3065. [21] Baker A, 2020. Fluorescence excitationemission matrix characterization of some sewageimpacted rivers. Environ Sci Technol, 35: 948—953. [22] Leenheer J A, Crou233。在論文的寫作過(guò)程中，參考了專家學(xué)者們的有關(guān)著作和教育教學(xué)研究方面的雜志，引用了其中的不少資料，在此也一并致謝 ! 感謝在百忙之中評(píng)審本文的各位老師。 從兩個(gè)地區(qū)垃圾滲濾液三維熒光光譜圖隨垃圾堆放時(shí)間的變化規(guī)律來(lái)看，垃圾的堆放時(shí)間越長(zhǎng)，其滲濾液中類蛋白質(zhì)濃度越低，而類富里酸濃度越高，說(shuō)明垃圾中的蛋白類物質(zhì)在腐殖化進(jìn)程中易于降解，腐殖化產(chǎn)生各種腐殖質(zhì)。 共 13 頁(yè) 第 9 頁(yè) 0102030405060700 1000 2020 3000 4000 50000102030405060700 1000 2020 3000 4000 5000 0204060801001200 1000 2020 3000 4000 5000010203040506070800 1000 2020 3000 4000 50001k 10k 30k 01020304050600 1000 2020 3000 4000 5000 100k 圖 5 永川垃圾滲濾液的紅外光譜圖 從圖 6 可以看出，永川地區(qū)的紅外光譜圖中含有苯環(huán)等芳香烴官能團(tuán)，經(jīng)分析其含有 腐殖酸 等。 表 7 所表現(xiàn)的 Ex/Em 峰位置與相關(guān)參考文獻(xiàn)對(duì)應(yīng) [1920, 2225]。同時(shí)， 4 個(gè)地區(qū)垃圾滲濾液的三維熒光光譜圖也存在著明顯的差異， 4 種水體的 3DEEM 具 有不同的等高線圖、熒
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