南京大學(xué)結(jié)構(gòu)化學(xué)雙語-全文預(yù)覽
【正文】 d d2 2 2,z x ydd ? D 498 Group Theoretical Analysis Topics: ? Orbital splitting in Octahedral Field ? Splitting of Terms ? Weak Field Scheme（弱場方案） ? Strong Field Scheme （強(qiáng)場方案） 9 Orbital Splitting in Octahedral Field Atomic orbitals in zero field 上述基函數(shù)集合皆為中心對稱力場中的不可約 表示基函數(shù)。 6C4 3C2(C42) A1 1 1 1 1 1 A2 1 1 1 1 1 E 2 1 0 0 2 z2, x2y2 T1 3 0 1 1 1 x, y, z T2 3 0 1 1 1 xy, yz, zx 11 由群表直接可知： s = A1g p = T1u d = Eg+T2g 如何判斷七個 f原子軌道 , 和 F,G,H 等譜項的分裂呢 ? 12 ( , , ) ( ) ( ) ( )r R r? ? ? ? ?? ? ?Atomic orbital in general, If the rotations is about the zaxis, the only changes in the wavefunction is in ()??( ) ( )? ? ?? ? ? ?13 ? ( ) ( )R ? ? ?? ? ? ?? ( ) ( )imRe ???? ? ?????????????????????????????????????????????????????????????????????????????????????????????????????illiimliililliimliililliimliileeeeeeeeeeeeeeezR)1()1()1()1()1()1(00000000000000000000)(?????????????????????????????14 112222( ( ) ) ( ( ) ) i l i liie C e C e e?? ??? ? ? ?? ? ? ?? ? ?? ? ? ? ?? ? ? ?? ? ?1122221si n ( )2( ( ) )1si n2i l i liileeCee????????? ? ? ?? ? ?? ? ? ?? ? ? ??????????
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